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51.
This study aimed to test the performance of the amphipod Gammarus locusta (L.) in chronic sediment toxicity tests. It constitutes part of a multi-level assessment of chronic toxicity of estuarine sediments, integrating organism and population-level endpoints with biochemical markers responses. Here we account for organism and population-level effects, while biomarker responses were reported in a companion article. Five moderately contaminated sediments from Sado and Tagus estuaries were tested, comprising 3 muddy and 2 sandy sediments. These sediments either did not show acute toxicity or were diluted with control sediment as much as required to remove acute toxicity. Subsequent chronic tests consisted of 28-day exposures with survival, individual growth and reproductive traits as endpoints. Two of the muddy sediments induced higher growth rates in the amphipods, and improved reproductive traits. This was understood to be a consequence of the amount of organic matter in the sediment, which was nutritionally beneficial to the amphipods, while concurrently decreasing contaminant bioavailability. Biomarker responses did not reveal toxicant-induced stress in amphipods exposed to these sediments. One of the sandy sediments was acutely toxic at 50% dilution, but in contrast stimulated amphipod growth when diluted 75%. This was presumed to be an indication of a hormetic response. Finally the two remaining contaminated sediments showed pronounced chronic toxicity, affecting survival and reproduction. The sex ratio of survivors was highly biased towards females, and offspring production was severely impaired. The particulars of the responses of this amphipod were examined, as well as strengths versus limitations of the sediment test. This study illustrates the utility of this chronic test for toxicity assessment of contaminated estuarine sediments, with potential application all along Atlantic Europe.  相似文献   
52.
53.
This paper deals with the problem of detecting and correcting cycle-slips in Global Navigation Satellite System (GNSS) phase data by exploiting the Bayesian theory. The method is here applied to undifferenced observations, because repairing cycle-slips already at this stage could be a useful pre-processing tool, especially for a network of permanent GNSS stations. If a dual frequency receiver is available, the cycle-slips can be easily detected by combining two phase observations or phase and range observations from a single satellite to a single receiver. These combinations, expressed in a distance unit form, are completely free from the geometry and depend only on the ionospheric effect, on the electronic biases and on the initial integer ambiguities; since these terms are expected to be smooth in time, at least in a short period, a cycle-slip in one or both the two carriers can be modelled as a discontinuity in a polynomial regression. The proposed method consists in applying the Bayesian theory to compute the marginal posterior distribution of the discontinuity epoch and to detect it as a maximum a posteriori (MAP) in a very accurate way. Concerning the cycle-slip correction, a couple of simultaneous integer slips in the two carriers is chosen by maximazing the conditional posterior distribution of the discontinuity amplitude given the detected epoch. Numerical experiments on simulated and real data show that the discontinuities with an amplitude 2 or 3 times larger than the noise standard deviation are successfully identified. This means that the Bayesian approach is able to detect and correct cycle-slips using undifferenced GNSS observations even if the slip occurs by one cycle. A comparison with the scientific software BERNESE 5.0 confirms the good performance of the proposed method, especially when data sampled at high frequency (e.g. every 1 s or every 5 s) are available.  相似文献   
54.
New geologic mapping of the area near Castellamonte (Torino Province) describes a wide Plio-Quaternary continental succession, up to about 100-m thick. This sequence is distinguished according to allostratigraphic criteria. Altitude, degree of pedogenesis and sediment supply from different basins are also used. Within a single alloformation, several lithofacies are described.Fine-grained fan-delta sediments (Vespia Alloformation) are described in the lower part of the continental succession. The fossil plant remains indicate an Early–Middle Pliocene age. These sediments show an evident deformation and fill ancient lacustrine basins, likely associated with the Canavese Line trend. Their wide distribution and considerable thickness suggest subsidence.Coarse-grained glacial, outwash and fluvial sediments (Colleretto Castelnuovo, S. Defendente, Case Musso, Pagliero, Serra and Piverone Alloformations) are described in the upper part of the continental succession. They consist of undeformed sediments deposited during Middle to Late Pleistocene. These sediments indicate the presence of small local glaciers along the current valley trends. The terracing ratios among the different units and their small thicknesses indicate subsequent differential uplift.  相似文献   
55.
The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO3 and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO2 contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ13CTDIC values suggest the presence of two distinct CO2 sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO2 and He indicates an increased mantle signature in uprising CO2-rich fluids.  相似文献   
56.
Turbidites crop out extensively in the Northern Apennine mountains (Italy). The huge amounts of groundwater drained by tunnels, built for the high speed railway connection between Bologna and Florence, demonstrate the aquifer-like behaviour of these units, up to now considered as aquitards. A conceptual model of groundwater flow systems (GFS) in fractured aquifers of turbidites is proposed, taking into account both system natural state and the perturbation induced by tunnel drainage. Analysis of hydrological data (springs, streams and tunnel discharge), collected over 10 years, was integrated with analysis of hydrochemical and isotopic data and a stream-tunnel tracer test. Hydrologic recession analysis of undisturbed conditions is a key tool in studying turbiditic aquifer hydrogeology, permitting the discrimination of GFS, the estimation of recharge relative to the upstream reach portion and the identification of springs most vulnerable to tunnel drainage impacts. The groundwater budgeting analysis provides evidence that the natural aquifer discharge was stream-focused through GFS, developed downslope or connected to main extensional tectonic lineaments intersecting stream beds; now tunnels drain mainly active recharge groundwater and so cause a relevant stream baseflow deplenishment (approximately two-thirds of the natural value), possibly resulting in adverse effects on local ecosystems.  相似文献   
57.
The large-scale crustal deformations observed in the Central European Basin System (CEBS) are the result of the interplay between several controlling factors, among which lateral rheological heterogeneities play a key role. We present a finite-element integral thin sheet model of stress and strain distribution within the CEBS. Unlike many previous models, this study is based on thermo-mechanical data to quantify the impact of lateral contrasts on the tectonic deformation. Elasto-plastic material behaviour is used for both the mantle and the crust, and the effects of the sedimentary fill are also investigated. The consistency of model results is ensured through comparisons with observed data. The results resemble the present-day dynamics and kinematics when: (1) a weak granite-like lower crust below the Elbe Fault System is modelled in contrast to a stronger lower crust in the area extending north of the Elbe Line throughout the Baltic region; and (2) a transition domain in the upper mantle is considered between the shallow mantle of the Variscan domain and the deep mantle beneath the East European Craton (EEC), extending from the Elbe Line in the south till the Tornquist Zone. The strain localizations observed along these structural contrasts strongly enhance the dominant role played by large structural domains in stiffening the propagation of tectonic deformation and in controlling the basin formation and the evolution in the CEBS.  相似文献   
58.
As part of the Yangtze plate, segments of the Dabie Shan terrane of Central China underwent ultra-high pressure metamorphism during Triassic subduction. We studied the geochemistry of the abundant eclogites to evaluate the nature of the protoliths and their geodynamic setting. Although some previous geochemical work exists, the analyses and interpretation herein are based on a new subdivision of the ultra-high pressure sequence into basement and cover units (Changpu and Ganghe Unit), revealing new and important results. In addition, eclogites of the so-called HP Unit south of the UHP units were studied. Whereas the large ion lithophile elements indicate postmagmatic, metasomatic changes of some samples, the high-field strength elements and the rare earth elements display original magmatic trends. The geochemical characteristics of the eclogites of the ultra-high pressure areas display a strong dependence on their “structural” and geographic position. The eclogites of the basement and the Changpu Unit indicate melt intrusion and extrusion in a continental rift system, i.e. during extensional tectonics. In contrast, the Ganghe Unit is characterized by a pronounced chemical homogeneity. The composition of the eclogites indicates generation from a mantle source highly influenced by slab-derived fluids. Those of the HP Unit show similar characteristics. Magmatism of the Ganghe and HP Unit probably occurred in a continental arc setting. A similar age for both units, geographically and/or tectonically separated, is possible. The geodynamic interpretation based on the geochemistry of the four units points to a Neoproterozoic scenario in which the protoliths of the HP and the cover units could have been of similar age and deposited in one evolving geological system. A rift-related larger-scale basin might have formed, e.g. a continental back-arc basin behind a magmatic arc after or simultaneous to sedimentation and magmatism in the magmatic arc. Alternatively, magmatism occurred in independent geodynamic settings, distinct in time and space. The units were juxtaposed during exhumation, after subduction to varying depths.  相似文献   
59.
The accurate prediction of runout distances, velocities and the knowledge of flow rheology can reduce the casualties and property damage produced by debris flows, providing a means to delineate hazard areas, to estimate hazard intensities for input into risk studies and to provide parameters for the design of protective measures. The application of most of models that describe the propagation and deposition of debris flow requires detailed topography, rheological and hydrological data that are not always available for the debris-flow hazard delineation and estimation. In the Cortina d’Ampezzo area, Eastern Dolomites, Italy, most of the slope instabilities are represented by debris flows; 325 debris-flow prone watersheds have been mapped in the geomorphological hazard map of this area. We compared the results of simulations of two well-documented debris flows in the Cortina d’Ampezzo area, carried on with two different single-phase, non-Newtonian models, the one-dimensional DAN-W and the two-dimensional FLO-2D, to test the possibility to simulate the dynamic behaviour of a debris flow with a model using a limited range of input parameters. FLO-2D model creates a more accurate representation of the hazard area in terms of flooded area, but the results in terms of runout distances and deposits thickness are similar to DAN-W results. Using DAN-W, the most appropriate rheology to describe the debris-flow behaviour is the Voellmy model. When detailed topographical, rheological and hydrological data are not available, DAN-W, which requires less detailed data, is a valuable tool to predict debris-flow hazard. Parameters obtained through back-analysis with both models can be applied to predict hazard in other areas characterized by similar geology, morphology and climate.  相似文献   
60.
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ~ 840 μg g?1 U (Th/U ~ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   
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